Utilization of Sc3N@C80 in long-range charge transfer reactions

Silke Wolfrum; Julio R. Pinzón; Agustin Molina-Ontoria; Andreas Gouloumis; Nazario Martín; Luis Echegoyen; Dirk M. Guldi

doi:10.1039/C0CC04159A

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Utilization of Sc₃N@C₈₀ in long-range charge transfer reactions†

Silke Wolfrum,^a Julio R. Pinzón,^b Agustin Molina-Ontoria,^cd Andreas Gouloumis,^cd Nazario Martín,*^cd Luis Echegoyen*^e and Dirk M. Guldi*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, 91058 Erlangen, Germany
E-mail: silke.wolfrum@chemie.uni-erlangen.de, guldi@chemie.uni-erlangen.de

^b Department of Chemistry, Clemson University, Clemson, SC, USA
E-mail: jpinzon@clemson.edu
Fax: +1 864 656 6613

^c Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense, 28040 Madrid, Spain
E-mail: nazmar@quim.ucm.es

^d IMDEA-Nanociencia, Campus de Cantoblanco, 28049 Madrid, Spain

^e Department of Chemistry, University of Texas at El Paso, El Paso, TX, USA
E-mail: echegoyen@utep.edu
Fax: +1 915 747-8807

Abstract

Electron accepting Sc₃N@C₈₀ promotes long-range charge transfer events evolving from photoexcited metalloporphyrins to afford radical ion pair states with lifetimes in the range of μs.

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Article information

DOI: https://doi.org/10.1039/C0CC04159A
Article type: Communication
Submitted: 30 Sep 2010
Accepted: 24 Nov 2010
First published: 15 Dec 2010

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Chem. Commun., 2011,47, 2270-2272

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Utilization of Sc₃N@C₈₀ in long-range charge transfer reactions

S. Wolfrum, J. R. Pinzón, A. Molina-Ontoria, A. Gouloumis, N. Martín, L. Echegoyen and D. M. Guldi, Chem. Commun., 2011, 47, 2270 DOI: 10.1039/C0CC04159A

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