Issue 1, 2011
From the journal:

Chemical Communications

Site-specific introduction of gold-carbenoids by intermolecular oxidation of ynamides or ynol ethers†‡

Paul W. Davies,*a   Alex Cremonesia  and  Nicolas Martina  

* Corresponding authors

a School of Chemistry, University of Birmingham, Edgbaston, Birmingham, UK
E-mail: p.w.davies@bham.ac.uk
Tel: +44 (0)121 4144408

Abstract

Ynamides and ynol ethers undergo intermolecular gold-catalysed reaction with a nucleophilic oxidant to access metal-carbenoid reactivity patterns. A site-specific oxidation/1,2-insertion cascade is used for a general access to functionalised α,β-unsaturated carboxylic acid derivatives and vinylogous carbimates.

Graphical abstract: Site-specific introduction of gold-carbenoids by intermolecular oxidation of ynamides or ynol ethers

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Article information

DOI
https://doi.org/10.1039/C0CC02736G
Article type
Communication
Submitted
22 Jul 2010
Accepted
17 Aug 2010
First published
08 Sep 2010

Chem. Commun., 2011,47, 379-381

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Site-specific introduction of gold-carbenoids by intermolecular oxidation of ynamides or ynol ethers

P. W. Davies, A. Cremonesi and N. Martin, Chem. Commun., 2011, 47, 379 DOI: 10.1039/C0CC02736G

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