Issue 1, 2011
From the journal:

Chemical Communications

Transforming terpene feedstock into polyketide architecture†‡

Philipp Winter,a   Carine Vaxelaire,a   Christoph Heinza  and  Mathias Christmann*a  

* Corresponding authors

a TU Dortmund University, Otto-Hahn-Str. 6, D-44227 Dortmund, Germany
E-mail: mathias.christmann@udo.edu
Fax: +49 231 755 5363
Tel: +49 231 755 7854

Abstract

The Cu-catalyzed synthesis of skipped 1,4-dienes from allylic acetates and vinyl-Grignard reagents is key to bidirectional modifications of acyclic terpene acetates. As a result, trisubstituted double bond containing subunits can be readily transferred into complex polyketides from inexpensive bulk terpenes.

Graphical abstract: Transforming terpene feedstock into polyketide architecture

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Article information

DOI
https://doi.org/10.1039/C0CC02332A
Article type
Communication
Submitted
02 Jul 2010
Accepted
24 Aug 2010
First published
10 Sep 2010

Chem. Commun., 2011,47, 394-396

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Transforming terpene feedstock into polyketide architecture

P. Winter, C. Vaxelaire, C. Heinz and M. Christmann, Chem. Commun., 2011, 47, 394 DOI: 10.1039/C0CC02332A

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