Issue 1, 2011
From the journal:

Chemical Communications

Double addition of H2 to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres†‡

Nikolaos Tsoureas,a   Yu-Ying Kuo,a   Mairi F. Haddowa  and  Gareth R. Owen§*a  

* Corresponding authors

a The School of Chemistry, University of Bristol, Bristol, UK
E-mail: gareth.owen@bristol.ac.uk
Fax: +44 (0)117 925 1295
Tel: +44 (0)117 928 7652

Abstract

The addition of H2 across a transition metal–borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride.

Graphical abstract: Double addition of H2 to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

  • This article is part of the themed collection: Hydrogen
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Article information

DOI
https://doi.org/10.1039/C0CC02245D
Article type
Communication
Submitted
30 Jun 2010
Accepted
23 Sep 2010
First published
11 Oct 2010

Chem. Commun., 2011,47, 484-486

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Double addition of H2 to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

N. Tsoureas, Y. Kuo, M. F. Haddow and G. R. Owen, Chem. Commun., 2011, 47, 484 DOI: 10.1039/C0CC02245D

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