Issue 4, 2010

Determination of the propagation rate coefficient of acrylonitrile

Abstract

For the first time, the propagation rate coefficient kp of acrylonitrile has been determined in a broad temperature range in propylene carbonate solution via the pulsed laser polymerizationsize exclusion chromatography technique employing a high frequency pulsed laser system. kp was determined to fit the Arrhenius relation ln(kp/L mol−1 s−1) = 14.42 − 1855K/T.

Graphical abstract: Determination of the propagation rate coefficient of acrylonitrile

Supplementary files

Article information

Article type
Communication
Submitted
18 Jan 2010
Accepted
08 Feb 2010
First published
04 Mar 2010

Polym. Chem., 2010,1, 438-441

Determination of the propagation rate coefficient of acrylonitrile

T. Junkers, S. P. S. Koo and C. Barner-Kowollik, Polym. Chem., 2010, 1, 438 DOI: 10.1039/C0PY00019A

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