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Issue 4, 2010
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Determination of the propagation rate coefficient of acrylonitrile

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Abstract

For the first time, the propagation rate coefficient kp of acrylonitrile has been determined in a broad temperature range in propylene carbonate solution via the pulsed laser polymerizationsize exclusion chromatography technique employing a high frequency pulsed laser system. kp was determined to fit the Arrhenius relation ln(kp/L mol−1 s−1) = 14.42 − 1855K/T.

Graphical abstract: Determination of the propagation rate coefficient of acrylonitrile

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Article information


Submitted
18 Jan 2010
Accepted
08 Feb 2010
First published
04 Mar 2010

Polym. Chem., 2010,1, 438-441
Article type
Communication

Determination of the propagation rate coefficient of acrylonitrile

T. Junkers, S. P. S. Koo and C. Barner-Kowollik, Polym. Chem., 2010, 1, 438
DOI: 10.1039/C0PY00019A

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