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Issue 22, 2010
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New fluorescent trans-dihydrofluoren-3-ones from aldol–Robinson annulation–regioselective addition involved one-pot reaction

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Abstract

An unexpected discovery of new trans-4-acetyl-1,9-dimethyl-4,4a-dihydro-3H-fluoren-3-ones from one pot reactions of benzaldehydes and acetylacetone is described. The synthetic mechanism and stereochemistry were discussed. These new derivatives exhibit good fluorescent properties in solutions.

Graphical abstract: New fluorescent trans-dihydrofluoren-3-ones from aldol–Robinson annulation–regioselective addition involved one-pot reaction

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Publication details

The article was received on 08 Jul 2010, accepted on 10 Aug 2010 and first published on 06 Sep 2010


Article type: Communication
DOI: 10.1039/C0OB00401D
Citation: Org. Biomol. Chem., 2010,8, 5048-5052

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    New fluorescent trans-dihydrofluoren-3-ones from aldol–Robinson annulation–regioselective addition involved one-pot reaction

    Y. Huo, X. Qiu, W. Shao, J. Huang, Y. Yu, Y. Zuo, L. An, J. Du and X. Bu, Org. Biomol. Chem., 2010, 8, 5048
    DOI: 10.1039/C0OB00401D

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