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Issue 23, 2010
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Chiral BINOL-derived phosphoric acids: privileged Brønsted acid organocatalysts for C–C bond formation reactions

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Abstract

BINOL-derived phosphoric acids have emerged during the last five years as powerful chiral Brønsted acid catalysts in many enantioselective processes. The most successful transformations carried out with chiral BINOL phosphates include C–C bond formation reactions. The recent advances have been reviewed in this article with a focus being placed on hydrocyanations, aldol-type, Mannich, Friedel–Crafts, aza-ene-type, Diels–Alder, as well as cascade and multi-component reactions.

Graphical abstract: Chiral BINOL-derived phosphoric acids: privileged Brønsted acid organocatalysts for C–C bond formation reactions

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Article information


Submitted
04 Jun 2010
Accepted
27 Jul 2010
First published
06 Sep 2010

Org. Biomol. Chem., 2010,8, 5262-5276
Article type
Perspective

Chiral BINOL-derived phosphoric acids: privileged Brønsted acid organocatalysts for C–C bond formation reactions

A. Zamfir, S. Schenker, M. Freund and S. B. Tsogoeva, Org. Biomol. Chem., 2010, 8, 5262 DOI: 10.1039/C0OB00209G

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