Issue 21, 2010

NHC-catalysed annulation of enals to tethered dienones: efficient synthesis of bicyclic dienes

Abstract

Homoenolates generated from α,β-unsaturated aldehydes using NHC catalysis underwent facile addition to dibenzylidene cyclohexanone to afford bicyclic cyclopentenes as single diastereomers.

Graphical abstract: NHC-catalysed annulation of enals to tethered dienones: efficient synthesis of bicyclic dienes

Supplementary files

Article information

Article type
Paper
Submitted
27 May 2010
Accepted
01 Jul 2010
First published
24 Aug 2010

Org. Biomol. Chem., 2010,8, 4861-4866

NHC-catalysed annulation of enals to tethered dienones: efficient synthesis of bicyclic dienes

V. Nair, S. Vellalath, B. P. Babu, V. Varghese, R. R. Paul and E. Suresh, Org. Biomol. Chem., 2010, 8, 4861 DOI: 10.1039/C0OB00180E

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