Issue 21, 2010
From the journal:

Organic & Biomolecular Chemistry

NHC-catalysed annulation of enals to tethered dienones: efficient synthesis of bicyclic dienes†

Vijay Nair,*a   Sreekumar Vellalath,a   Beneesh P. Babu,a   Vimal Varghese,a   Rony Rajan Paula  and  Eringathodi Sureshb  

* Corresponding authors

a Organic Chemistry Section, National Institute for Interdisciplinary Science and Technology (NIIST), Thiruvananthapuram, Kerala, India
E-mail: vijaynair_2001@yahoo.com
Fax: 91-471-2491712
Tel: 91-471-2490406

b Analytical Science Division, Central Salt and Marine Chemicals Research Institute, Bhavnagar, Gujarat, India

Abstract

Homoenolates generated from α,β-unsaturated aldehydes using NHC catalysis underwent facile addition to dibenzylidene cyclohexanone to afford bicyclic cyclopentenes as single diastereomers.

Graphical abstract: NHC-catalysed annulation of enals to tethered dienones: efficient synthesis of bicyclic dienes

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Article information

DOI
https://doi.org/10.1039/C0OB00180E
Article type
Paper
Submitted
27 May 2010
Accepted
01 Jul 2010
First published
24 Aug 2010

Org. Biomol. Chem., 2010,8, 4861-4866

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NHC-catalysed annulation of enals to tethered dienones: efficient synthesis of bicyclic dienes

V. Nair, S. Vellalath, B. P. Babu, V. Varghese, R. R. Paul and E. Suresh, Org. Biomol. Chem., 2010, 8, 4861 DOI: 10.1039/C0OB00180E

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