Issue 18, 2010

Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)2/HPMoV/O2 system

Abstract

A facile direct synthesis of cinnamonitriles from acrylonitriles and benzenes is successfully achieved by using Pd(OAc)2/HPMoV/O2 catalyst system via the direct C–H bond activation of benzenes using molecular oxygen as a terminal oxidant.

Graphical abstract: Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)2/HPMoV/O2 system

Supplementary files

Article information

Article type
Communication
Submitted
27 May 2010
Accepted
07 Jul 2010
First published
23 Jul 2010

Org. Biomol. Chem., 2010,8, 4071-4073

Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)2/HPMoV/O2 system

Y. Obora, Y. Okabe and Y. Ishii, Org. Biomol. Chem., 2010, 8, 4071 DOI: 10.1039/C0OB00176G

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