Issue 10, 2010
From the journal:

Organic & Biomolecular Chemistry

Anodic oxidation of catechols in the presence of α-oxoketene N,N-acetals with a tetrahydropyrimidine ring: selective α-arylation reaction†

Cheng-Chu Zeng,*a   Da-Wei Ping,a   Li-Ming Hu,a   Xiu-Qing Songa  and  Ru-Gang Zhonga  

* Corresponding authors

a College of Life Science & Bioengineering, Beijing University of Technology, Beijing, China
E-mail: zengcc@bjut.edu.cn
Fax: 00 86 10-67392001

Abstract

The electrochemical oxidation of catechols leads to the formation of o-benzoquinones. This property has been applied to effectively synthesize α-arylated products of α-oxoketene N,N-acetals with a tetrahydropyrimidine ring.

Graphical abstract: Anodic oxidation of catechols in the presence of α-oxoketene N,N-acetals with a tetrahydropyrimidine ring: selective α-arylation reaction

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Article information

DOI
https://doi.org/10.1039/C001847C
Article type
Paper
Submitted
01 Feb 2010
Accepted
12 Mar 2010
First published
24 Mar 2010

Org. Biomol. Chem., 2010,8, 2465-2472

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Anodic oxidation of catechols in the presence of α-oxoketene N,N-acetals with a tetrahydropyrimidine ring: selective α-arylation reaction

C. Zeng, D. Ping, L. Hu, X. Song and R. Zhong, Org. Biomol. Chem., 2010, 8, 2465 DOI: 10.1039/C001847C

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