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Issue 11, 2010
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A two-fold interpenetrated (3,6)-connected metal–organic framework with rutile topology showing a large solvent cavity

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Abstract

A two-fold interpenetrated metal–organic framework (MOF), [(Zn4O)2L4(DMF)2(H2O)3], was prepared using the tritopic ligand 4,4′,4′′-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid (H3L) and zinc nitrate. The MOF, based on the hexatopic tetranuclear Zn4O(COO)6 secondary building unit, has a (3,6)-connected network with an rtl topology and a large solvent cavity.

Graphical abstract: A two-fold interpenetrated (3,6)-connected metal–organic framework with rutile topology showing a large solvent cavity

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Publication details

The article was received on 13 Apr 2010, accepted on 18 Jun 2010 and first published on 26 Jul 2010


Article type: Letter
DOI: 10.1039/C0NJ00272K
Citation: New J. Chem., 2010,34, 2396-2399
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    A two-fold interpenetrated (3,6)-connected metal–organic framework with rutile topology showing a large solvent cavity

    X. Song, Y. Zou, X. Liu, M. Oh and M. S. Lah, New J. Chem., 2010, 34, 2396
    DOI: 10.1039/C0NJ00272K

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