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Issue 8, 2010
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A 1,1′-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

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Abstract

The new ambiphilic ligand Ph2P–(1,1′-ferrocenyl)–BMes2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative PB and FeB interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.

Graphical abstract: A 1,1′-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

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Publication details

The article was received on 12 Feb 2010, accepted on 18 Mar 2010 and first published on 13 Apr 2010


Article type: Letter
DOI: 10.1039/C0NJ00117A
Citation: New J. Chem., 2010,34, 1556-1559
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    A 1,1′-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

    M. W. P. Bebbington, S. Bontemps, G. Bouhadir, M. J. Hanton, R. P. Tooze, H. van Rensburg and D. Bourissou, New J. Chem., 2010, 34, 1556
    DOI: 10.1039/C0NJ00117A

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