Issue 8, 2010
From the journal:

New Journal of Chemistry

A 1,1′-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation†‡§

Magnus W. P. Bebbington,a   Sébastien Bontemps,||a   Ghenwa Bouhadir,a   Martin J. Hanton,b   Robert P. Tooze,b   Hendrick van Rensburgb  and  Didier Bourissou*a  

* Corresponding authors

a Université de Toulouse, UPS, LHFA, and CNRS, LHFA UMR 5069, 118 route de Narbonne, 31062 Toulouse, France
E-mail: dbouriss@chimie.ups-tlse.fr
Fax: +33 5-6155-8204
Tel: +33 (0)561557737

b Sasol Technology UK, Purdie Building, North Haugh, St Andrews, UK

Abstract

The new ambiphilic ligand Ph2P–(1,1′-ferrocenyl)–BMes2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.

Graphical abstract: A 1,1′-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

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Article information

DOI
https://doi.org/10.1039/C0NJ00117A
Article type
Letter
Submitted
12 Feb 2010
Accepted
18 Mar 2010
First published
13 Apr 2010

New J. Chem., 2010,34, 1556-1559

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A 1,1′-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

M. W. P. Bebbington, S. Bontemps, G. Bouhadir, M. J. Hanton, R. P. Tooze, H. van Rensburg and D. Bourissou, New J. Chem., 2010, 34, 1556 DOI: 10.1039/C0NJ00117A

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