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Issue 8, 2010
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Dithienophosphole-capped π-conjugated oligomers

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Abstract

The synthesis of a 2-monobrominated dithieno[3,2-b:2′,3′-d]phosphole has opened the access to a series of highly luminescent π-conjugated oligomers that link two dithienophosphole units via a variety of aromatic spacers. The nature of the linking mode was found to have a significant impact on the photophysical properties of the system as a whole, either considerably improving the molar absorptivity of the new extended chromophores, or providing luminescent materials with red-shifted emission features and substantial photoluminescence quantum yields.

Graphical abstract: Dithienophosphole-capped π-conjugated oligomers

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Publication details

The article was received on 15 Jan 2010, accepted on 02 Mar 2010 and first published on 31 Mar 2010


Article type: Paper
DOI: 10.1039/C0NJ00026D
Citation: New J. Chem., 2010,34, 1585-1592
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    Dithienophosphole-capped π-conjugated oligomers

    S. Durben, T. Linder and T. Baumgartner, New J. Chem., 2010, 34, 1585
    DOI: 10.1039/C0NJ00026D

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