Issue 8, 2010
From the journal:

New Journal of Chemistry

2-(2′-Pyridyl)-4,6-diphenylphosphinineversus2-(2′-pyridyl)-4,6-diphenylpyridine: an evaluation of their coordination chemistry towards Rh(i)†‡

Ariadna Campos Carrasco,a   Evgeny A. Pidko,b   Anna M. Masdeu-Bultó,a   Martin Lutz,c   Anthony L. Spek,c   Dieter Vogtb  and  Christian Müller*b  

* Corresponding authors

a Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Marcel lí Domingo s/n, 43007 Tarragona, Spain
Fax: +34 977559563
Tel: +34 977558779

b Schuit Institute of Catalysis, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, 5600 MB Eindhoven, the Netherlands
E-mail: c.mueller@tue.nl
Fax: +31 40 245 5054
Tel: +31 40 247 3040

c Bijvoet Center for Biomolecular Research, Department of Crystal and Structural Chemistry, Utrecht University, 3584 CH Utrecht, the Netherlands

Abstract

The coordination chemistry of the bidentate P,N hybrid ligand 2-(2′-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2′-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

Graphical abstract: 2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4,6-diphenylpyridine: an evaluation of their coordination chemistry towards Rh(i)

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Article information

DOI
https://doi.org/10.1039/C0NJ00030B
Article type
Letter
Submitted
15 Jan 2010
Accepted
17 Feb 2010
First published
24 Mar 2010

New J. Chem., 2010,34, 1547-1550

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2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4,6-diphenylpyridine: an evaluation of their coordination chemistry towards Rh(I)

A. C. Carrasco, E. A. Pidko, A. M. Masdeu-Bultó, M. Lutz, A. L. Spek, D. Vogt and C. Müller, New J. Chem., 2010, 34, 1547 DOI: 10.1039/C0NJ00030B

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