Li2B12H12·7NH3: a new ammine complex for ammonia storage or indirect hydrogen storage

Zhenguo Huang; Judith Gallucci; Xuenian Chen; Teshome Yisgedu; Hima Kumar Lingam; Sheldon G. Shore; Ji-Cheng Zhao

doi:10.1039/B923829H

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Li₂B₁₂H₁₂·7NH₃: a new ammine complex for ammoniastorage or indirect hydrogenstorage†

Zhenguo Huang,^a Judith Gallucci,^b Xuenian Chen,^b Teshome Yisgedu,^a Hima Kumar Lingam,^a Sheldon G. Shore^b and Ji-Cheng Zhao*^a

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* Corresponding authors

^a Department of Materials Science and Engineering, The Ohio State University, Columbus, OH, USA

^b Department of Chemistry, The Ohio State University, Columbus, OH, USA
E-mail: zhao.199@osu.edu

Abstract

A new ammine complex, Li₂B₁₂H₁₂·7NH₃, that can reversibly release all the NH₃ at below 200 °C and reabsorb NH₃ at room temperature and 0.5 bar was synthesized and investigated for reversible ammonia storage or indirect hydrogen storage.

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Article information

DOI: https://doi.org/10.1039/B923829H
Article type: Communication
Submitted: 13 Nov 2009
Accepted: 05 Feb 2010
First published: 25 Feb 2010

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J. Mater. Chem., 2010,20, 2743-2745

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Li₂B₁₂H₁₂·7NH₃: a new ammine complex for ammonia storage or indirect hydrogen storage

Z. Huang, J. Gallucci, X. Chen, T. Yisgedu, H. K. Lingam, S. G. Shore and J. Zhao, J. Mater. Chem., 2010, 20, 2743 DOI: 10.1039/B923829H

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Journal of Materials Chemistry