Issue 8, 2010
From the journal:

Green Chemistry

The solvent effect on the Diels–Alder reaction in ionic liquids: multiparameter linear solvation energy relationships and theoretical analysis

Cinzia Chiappe,*a   Marco Malvaldia  and  Christian Silvio Pomellia  

* Corresponding authors

a Dipartimento di Chimica e Chimica Industriale, Università di Pisa, via Risorgimento 35, Pisa, Italy
E-mail: cinziac@farm.unipit.it
Fax: +39 050 2219660
Tel: +39 050 2219669

Abstract

This review illustrates how ionic liquid properties can affect Diels–Alder reactions. The mechanisms by which ionic solvents enhance the rate and selectivity of the reaction are discussed on the basis of correlation studies using empirical parameters and theoretical calculations.

Graphical abstract: The solvent effect on the Diels–Alder reaction in ionic liquids: multiparameter linear solvation energy relationships and theoretical analysis

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Article information

DOI
https://doi.org/10.1039/C0GC00074D
Article type
Critical Review
Submitted
03 May 2010
Accepted
08 Jun 2010
First published
06 Jul 2010

Green Chem., 2010,12, 1330-1339

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The solvent effect on the Diels–Alder reaction in ionic liquids: multiparameter linear solvation energy relationships and theoretical analysis

C. Chiappe, M. Malvaldi and C. S. Pomelli, Green Chem., 2010, 12, 1330 DOI: 10.1039/C0GC00074D

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