Issue 1, 2010
From the journal:

Green Chemistry

An unusual common ion effect promotes dissolution of metal salts in room-temperature ionic liquids: a strategy to obtain ionic liquids having organic–inorganic mixed cations

C. Chiappe,*a   M. Malvaldi,a   B. Melai,a   S. Fantini,b   U. Bardic  and  S. Caporalic  

* Corresponding authors

a Dipartimento di Chimica e Chimica Industriale, Università di Pisa, via Risorgimento 35, Pisa, Italy
E-mail: cinziac@farm.unipi.it

b Solvionic, site SNPE, Chemin de la Loge, 31078 Toulouse cedex 4, France

c Dipartimento di Chimica, Università di Firenze, via della Lastruccia 3, 50019 Sesto Fiorentino (FI), Italy

Abstract

A simple strategy has been reported to prepare new ionic liquids with binary systems of organic–inorganic cations exploiting the common ion effect, i.e. dissolving metal salts with organic or inorganic anions (bistriflylimide or nitrate) in ionic liquids bearing the same anions. The resulting concentrated solutions of metal cations in ionic environments, which may have great potential for electrochemical processes, have been characterized by X-Ray photoelectron spectroscopy (XPS) and electrospray ionization mass spectrometry (ESI-MS)

Graphical abstract: An unusual common ion effect promotes dissolution of metal salts in room-temperature ionic liquids: a strategy to obtain ionic liquids having organic–inorganic mixed cations

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Article information

DOI
https://doi.org/10.1039/B919111A
Article type
Paper
Submitted
05 May 2009
Accepted
07 Sep 2009
First published
23 Oct 2009

Green Chem., 2010,12, 77-80

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An unusual common ion effect promotes dissolution of metal salts in room-temperature ionic liquids: a strategy to obtain ionic liquids having organic–inorganic mixed cations

C. Chiappe, M. Malvaldi, B. Melai, S. Fantini, U. Bardi and S. Caporali, Green Chem., 2010, 12, 77 DOI: 10.1039/B919111A

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