Issue 1, 2010
From the journal:

Green Chemistry

Catalyst-free silylation of alcohols and phenols by promoting HMDS in CH3NO2 as solvent†

Santosh T. Kadama  and  Sung Soo Kim*a  

* Corresponding authors

a Department of Chemistry, Inha University, Incheon, South Korea
E-mail: sungsoo@inha.ac.kr

Abstract

An uncatalyzed method for the silylation of alcohols and phenols with HMDS in CH3NO2 at rt is developed. A diverse range of aromatic and aliphatic alcohols as well as phenols undergo the silylation in very short reaction time with excellent yield. The uncatalyzed reaction requires neither elevated temperature nor high pressure for the silylation.

Graphical abstract: Catalyst-free silylation of alcohols and phenols by promoting HMDS in CH3NO2 as solvent

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B913398D
Article type
Paper
Submitted
08 Jul 2009
Accepted
17 Sep 2009
First published
26 Oct 2009

Green Chem., 2010,12, 94-98

Permissions

Request permissions

Catalyst-free silylation of alcohols and phenols by promoting HMDS in CH3NO2 as solvent

S. T. Kadam and S. S. Kim, Green Chem., 2010, 12, 94 DOI: 10.1039/B913398D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements