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Issue 44, 2010
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Gold- and silver-based ionic liquids: modulation of luminescence depending on the physical state

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Abstract

A series of gold- and silver-containing ionic liquids, [CnMIM][M(CN)2] (M = Au, Ag; n = 12, 14, 18), prepared by metathesis reactions, present luminescence depending on their physical state i.e. crystalline or smectic A phases. The photoluminescent measurements as well as DFT calculations suggest that the modulation of aurophilic intermolecular interactions are responsible for this phosphorescent behaviour.

Graphical abstract: Gold- and silver-based ionic liquids: modulation of luminescence depending on the physical state

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Publication details

The article was received on 01 Jun 2010, accepted on 30 Jul 2010 and first published on 04 Oct 2010


Article type: Communication
DOI: 10.1039/C0DT00583E
Citation: Dalton Trans., 2010,39, 10574-10576
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    Gold- and silver-based ionic liquids: modulation of luminescence depending on the physical state

    A. Tokarev, J. Larionova, Y. Guari, C. Guérin, J. M. López-de-Luzuriaga, M. Monge, P. Dieudonné and C. Blanc, Dalton Trans., 2010, 39, 10574
    DOI: 10.1039/C0DT00583E

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