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Issue 27, 2010
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Facile dihydrogen release from phosphino-borinate ester Lewis pairs

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Abstract

New phosphino-borinate ester Lewis pairs of the type tBu2PCH2C(R)2OB(C6F5)2 (R = Me or CF3) are synthesised from the corresponding phosphino-alcohol and HB(C6F5)2. Dihydrogen release from the zwitterionic tBu2PHCH2C(R)2OBH(C6F5)2 is facile.

Graphical abstract: Facile dihydrogen release from phosphino-borinate ester Lewis pairs

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Publication details

The article was received on 02 Feb 2010, accepted on 21 May 2010 and first published on 14 Jun 2010


Article type: Communication
DOI: 10.1039/C0DT00513D
Citation: Dalton Trans., 2010,39, 6184-6186
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    Facile dihydrogen release from phosphino-borinate ester Lewis pairs

    A. M. Chapman, M. F. Haddow, J. P. H. Orton and D. F. Wass, Dalton Trans., 2010, 39, 6184
    DOI: 10.1039/C0DT00513D

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