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Issue 22, 2010
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Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes

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Abstract

Abnormal isoxazolylidene complexes, a new subclass of mesoionic complexes containing an isoxazolium-derived carbene type ligand, have been synthesised via oxidative addition and compared to structurally related mesoionic complexes by using 31P NMR spectroscopy as a convenient probe for their donor ability and in catalytic cross-coupling reactions.

Graphical abstract: Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes

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Article information


Submitted
09 Dec 2009
Accepted
12 Mar 2010
First published
12 Apr 2010

Dalton Trans., 2010,39, 5213-5215
Article type
Communication

Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes

M. Iglesias and M. Albrecht, Dalton Trans., 2010, 39, 5213
DOI: 10.1039/C0DT00027B

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