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Issue 8, 2010
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Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions

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Abstract

We present new ureaphosphine ligands that coordinate in a P,O-bidentate fashion to rhodium(I). The ureaphosphine-Rh(I)-complexes were effectively used in the asymmetric hydrogenation of cyclic enamides giving high conversions and enantioselectivity.

Graphical abstract: Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions

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Article information


Submitted
09 Dec 2009
Accepted
17 Dec 2009
First published
06 Jan 2010

Dalton Trans., 2010,39, 1929-1931
Article type
Communication

Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions

J. Meeuwissen, R. J. Detz, A. J. Sandee, B. de Bruin and J. N. H. Reek, Dalton Trans., 2010, 39, 1929
DOI: 10.1039/B926043A

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