Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages

Takuya Shiga; Graham N. Newton; Jennifer S. Mathieson; Tamaki Tetsuka; Masayuki Nihei; Leroy Cronin; Hiroki Oshio

doi:10.1039/B925399H

Ferromagnetically coupled chiral cyanide-bridged {Ni₆Fe₄} cages

Takuya Shiga,^a Graham N. Newton,^a Jennifer S. Mathieson,^b Tamaki Tetsuka,^a Masayuki Nihei,^a Leroy Cronin^b and Hiroki Oshio*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Japan.
E-mail: oshio@chem.tsukuba.ac.jp
Fax: +81 29 853 4238
Tel: +81 29 853 4238

^b WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow, UK
E-mail: L.Cronin@chem.gla.ac.uk
Fax: +44-141-330-4888
Tel: +44-141-330-6650

Abstract

Enantiomeric, ferromagnetically coupled decanuclear {Ni₆Fe₄} cages with adamantane-like cores were synthesized around templating tetraethylammonium cations, as shown by crystallographic analysis and CSI-MS, and their homochiral nature was confirmed by circular dichroism measurements.

This article is part of the themed collection: Molecular magnets

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Publication details

The article was received on 02 Dec 2009, accepted on 08 Jan 2010 and first published on 21 Jan 2010

Article type: Communication

DOI: 10.1039/B925399H

Citation: Dalton Trans., 2010,39, 4730-4733

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Ferromagnetically coupled chiral cyanide-bridged {Ni₆Fe₄} cages

T. Shiga, G. N. Newton, J. S. Mathieson, T. Tetsuka, M. Nihei, L. Cronin and H. Oshio, Dalton Trans., 2010, 39, 4730
DOI: 10.1039/B925399H
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Dalton Transactions

Ferromagnetically coupled chiral cyanide-bridged {Ni₆Fe₄} cages

Abstract

Supplementary files

Publication details

Ferromagnetically coupled chiral cyanide-bridged {Ni₆Fe₄} cages

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