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Issue 9, 2010
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Optically induced cis-trans isomerisation of (η6-cis-stilbene)Cr(CO)3

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The femto- and picosecond time resolved spectroscopy of 6-cis-stilbene)Cr(CO)3 provides evidence for three optically accessible excited states one leading to cis-trans isomerisation of the coordinated stilbene ligand and another which results in a slow release of CO.

Graphical abstract: Optically induced cis-trans isomerisation of (η6-cis-stilbene)Cr(CO)3

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Publication details

The article was received on 04 Nov 2009, accepted on 15 Dec 2009 and first published on 12 Jan 2010

Article type: Communication
DOI: 10.1039/B925349C
Dalton Trans., 2010,39, 2201-2203

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    Optically induced cis-trans isomerisation of 6-cis-stilbene)Cr(CO)3

    A. C. Coleman, N. M. Boyle, C. Long, R. Augulis, A. Pugzlys, P. H. M. van Loosdrecht, W. R. Browne, B. L. Feringa, K. L. Ronayne and M. T. Pryce, Dalton Trans., 2010, 39, 2201
    DOI: 10.1039/B925349C

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