Issue 6, 2010
From the journal:

Dalton Transactions

P–C dichotomy: divergent iron(−I)-mediated alkyne and phosphaalkyne cycloligomerisations†

Robert Wolf,*a   Nugzar Ghavtadze,a   Katharina Weber,a   Eva-Maria Schnöckelborg,a   Bas de Bruin,b   Andreas W. Ehlersc  and  Koop Lammertsmac  

* Corresponding authors

a University of Münster, Institute of Inorganic and Analytical Chemistry, Corrensstr. 30, Germany
E-mail: r.wolf@uni-münster.de
Fax: (+49) 251-833-6610

b Van't Hoff Instiute of Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, The Netherlands

c Department of Organic and Inorganic Chemistry, Faculty of Sciences, VU University Amsterdam, De Boelelaan 1083, The Netherlands

Abstract

In contrast to the recently reported cyclodimerisations of phosphaalkynes, alkynes preferably trimerise at the same low-valent iron(−I) centre.

Graphical abstract: P–C dichotomy: divergent iron(−I)-mediated alkyne and phosphaalkyne cycloligomerisations

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Article information

DOI
https://doi.org/10.1039/B923663P
Article type
Communication
Submitted
21 Sep 2009
Accepted
17 Nov 2009
First published
04 Dec 2009

Dalton Trans., 2010,39, 1453-1456

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P–C dichotomy: divergent iron(−I)-mediated alkyne and phosphaalkyne cycloligomerisations

R. Wolf, N. Ghavtadze, K. Weber, E. Schnöckelborg, B. de Bruin, A. W. Ehlers and K. Lammertsma, Dalton Trans., 2010, 39, 1453 DOI: 10.1039/B923663P

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