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Issue 2, 2010
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Synthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands

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Abstract

This article describes the synthesis, characterization, and reactivity of palladium(II) fluoride complexes containing sp2 and sp3 nitrogen-containing supporting ligands. Both cis and trans complexes of general structure (N)(N′)PdII(R)(F) (R = Ar or CH3) as well as cis-(N)2PdII(F)2 are reported. Crystallographic characterization of these molecules has allowed structural comparisons to related phosphine-ligated species. Furthermore, these studies have revealed that nitrogen-donor ligands support some of the longest and the shortest Pd–F bonds reported to date. The thermal decomposition of (N)(N′)PdII(R)(F) has also been examined, and no products of C–F bond-forming reductive elimination were obtained in any case.

Graphical abstract: Synthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands

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Article information


Submitted
17 Jul 2009
Accepted
30 Sep 2009
First published
26 Nov 2009

Dalton Trans., 2010,39, 632-640
Article type
Paper

Synthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands

N. D. Ball, J. W. Kampf and M. S. Sanford, Dalton Trans., 2010, 39, 632
DOI: 10.1039/B914426A

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