Unique 3D self-penetrating CoII and NiII coordination frameworks with a new (44.610.8) network topology

Dong-Sheng Li; Feng Fu; Jun Zhao; Ya-Pan Wu; Miao Du; Kun Zou; Wen-Wen Dong; Yao-Yu Wang

doi:10.1039/C0DT00900H

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Unique 3D self-penetrating Co^II and Ni^II coordination frameworks with a new (4⁴.6¹⁰.8) network topology†

Dong-Sheng Li,*^ac Feng Fu,^a Jun Zhao,^a Ya-Pan Wu,^ac Miao Du,*^b Kun Zou,^a Wen-Wen Dong^ac and Yao-Yu Wang*^c

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* Corresponding authors

^a College of Mechanical & Material Engineering, Hubei Key Laboratory of Natural Products Research and Development, China Three Gorges University, Yichang, China
E-mail: lidongsheng1@126.com
Fax: +86-717-6397516
Tel: +86-717-6397516

^b College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin, China
E-mail: dumiao@public.tpt.tj.cn
Fax: +86-22-23766556
Tel: +86-22-23766556

^c Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry, Northwest University, Xi'an, China
E-mail: wyaoyu@nwu.edu.cn
Fax: +86-29-88303798
Tel: +86-29-88303798

Abstract

Two unique six-connected self-penetrating coordination polymers with a new (4⁴.6¹⁰.8) network topology, derived from the cross-linking of two 6⁶-dia subnets, were constructed from Ni^II or Co^II and two types of V-shaped tectons. The Ni^II complex 1 shows an antiferromagnetic coupling via μ-carboxylate and μ-H₂O pathways, whereas the Co^II complex 2 exhibits the single-ion behavior in 300–34 K and then a ferromagnetic coupling at lower temperatures.

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Article information

DOI: https://doi.org/10.1039/C0DT00900H
Article type: Communication
Submitted: 23 Jul 2010
Accepted: 05 Oct 2010
First published: 09 Nov 2010

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Dalton Trans., 2010,39, 11522-11525

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Unique 3D self-penetrating Co^II and Ni^II coordination frameworks with a new (4⁴.6¹⁰.8) network topology

D. Li, F. Fu, J. Zhao, Y. Wu, M. Du, K. Zou, W. Dong and Y. Wang, Dalton Trans., 2010, 39, 11522 DOI: 10.1039/C0DT00900H

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