Electrophilic activation and the formation of an unusual Tl+/Cr3+ tetranuclear ion-complex adduct

Shaofeng Liu; Riccardo Peloso; Roberto Pattacini; Pierre Braunstein

doi:10.1039/C0DT00810A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Electrophilic activation and the formation of an unusual Tl⁺/Cr³⁺ tetranuclear ion-complex adduct†

Shaofeng Liu,^ab Riccardo Peloso,†^a Roberto Pattacini^a and Pierre Braunstein*^a

Author affiliations

* Corresponding authors

^a Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, Strasbourg Cedex, France
E-mail: braunstein@unistra.fr
Fax: (+33) 3-6885-1322

^b Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China

Abstract

Reaction of TlPF₆ with the Cr(III) complex fac-[CrCl₃(NPN)] (NPN = bis(2-picolyl)phenyl phosphine) did not lead to precipitation of TlCl but rather to addition of the Tl⁺ cation to the CrCl₃ moiety, which resulted in a pseudo-dimeric adduct which has an unusual tetranuclear centrosymmetric structure in the solid state.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C0DT00810A
Article type: Communication
Submitted: 08 Jul 2010
Accepted: 16 Jul 2010
First published: 03 Aug 2010

Download Citation

Dalton Trans., 2010,39, 7881-7883

Permissions

Request permissions

Electrophilic activation and the formation of an unusual Tl⁺/Cr³⁺ tetranuclear ion-complex adduct

S. Liu, R. Peloso, R. Pattacini and P. Braunstein, Dalton Trans., 2010, 39, 7881 DOI: 10.1039/C0DT00810A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions