Issue 42, 2010
From the journal:

Dalton Transactions

Tetranuclear organometallic complexes containing Mo2O42+ and allylmolybdenum(ii) moieties†

Paloma Paredes,a   Angel López-Calzada,a   Daniel Miguela  and  Fernando Villafañe*a  

* Corresponding authors

a IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, Valladolid, Spain
E-mail: fervilla@qi.uva.es

Abstract

Refluxing toluene solutions of [Mo(η3-allyl)(O2CMe)(CO)2(pz*H)2] (pz*H = pzH, pyrazole, or dmpzH, 3,5-dimethylpyrazole) without exclusion of air, give the tetranuclear complexes [Mo2O2(O2CCH3)2{(μ3-O)(μ-pz*)Mo(η3-allyl)(CO)2(pz*H)}2], where two chelating acetato ligands and two “Mo(η3-allyl)(CO)2(pz*H)(μ-pz*)” fragments are bonded to a central Mo2O42+ moiety.

Graphical abstract: Tetranuclear organometallic complexes containing Mo2O42+ and allylmolybdenum(ii) moieties

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Article information

DOI
https://doi.org/10.1039/C0DT00570C
Article type
Paper
Submitted
28 May 2010
Accepted
26 Jul 2010
First published
20 Sep 2010

Dalton Trans., 2010,39, 10099-10104

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Tetranuclear organometallic complexes containing Mo2O42+ and allylmolybdenum(II) moieties

P. Paredes, A. López-Calzada, D. Miguel and F. Villafañe, Dalton Trans., 2010, 39, 10099 DOI: 10.1039/C0DT00570C

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