Issue 42, 2010
From the journal:

Dalton Transactions

Isolation and reactivity of an unusually stable organoselenenyl azide†

Kriti Srivastava,a   Tapash Chakraborty,a   Harkesh B. Singh,*a   Udai P. Singhb  and  Ray J. Butcherc  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Bombay, Powai, India
E-mail: chhbsia@ chem.iitb.ac.in
Fax: (+91)22-2572-3480
Tel: 022-2576 7190

b Department of Chemistry Indian Institute of Technology Roorkee, India
E-mail: udaipfcy@iitr.ernet.in
Tel: 91-01332-285329

c Department of Chemistry, Howard University, Washington D.C., USA

Abstract

The stabilities of a series of isolated covalent selenium(II) azides such as [2-[1-(3,5-dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]selenium azide (2a), [2-(4,4-dimethyl-2-oxazolinyl)phenyl]selenenyl azide (3a), [o-(2,6-diisopropylphenyl-iminomethinyl)phenyl]selenenyl azide (4a), [o-(R)-(methylbenzyliminomethinyl)phenyl]selenenyl azide (5a) and o-formylphenylselenenyl azide (6a) are rationalized; also the reactivity of first room temperature stable azide (2a) toward 1,3-cycloaddition has been explored.

Graphical abstract: Isolation and reactivity of an unusually stable organoselenenyl azide

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Article information

DOI
https://doi.org/10.1039/C0DT00509F
Article type
Paper
Submitted
20 May 2010
Accepted
16 Jul 2010
First published
13 Sep 2010

Dalton Trans., 2010,39, 10137-10141

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Isolation and reactivity of an unusually stable organoselenenyl azide

K. Srivastava, T. Chakraborty, H. B. Singh, U. P. Singh and R. J. Butcher, Dalton Trans., 2010, 39, 10137 DOI: 10.1039/C0DT00509F

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