Issue 40, 2010
From the journal:

Dalton Transactions

Synthesis, structures and electrochemistry studies of 2Fe2S–Fe(ii)(S–2N)2 models for H-cluster of [FeFe]-hydrogenase†

Ming-Qiang Hu,a   Hui-min Wen,a   Cheng-Bing Ma,a   Na Li,a   Qing-Yun Yan,a   Hui Chena  and  Chang-Neng Chen*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P.R.China
E-mail: ccn@fjirsm.ac.cn
Fax: +86-591-83792395

Abstract

A series of model complexes [(μ-pdt)Fe2(CO)5]2M(sip)2 (M = Fe, Ni) were synthesized as H-cluster analogues of [FeFe]-hydrogenase. Their electrochemical behaviours were investigated and it is proposed that the bridging metal bis(tris-chelate) groups act as electron transfer sites in theses mimics.

Graphical abstract: Synthesis, structures and electrochemistry studies of 2Fe2S–Fe(ii)(S–2N)2 models for H-cluster of [FeFe]-hydrogenase

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Article information

DOI
https://doi.org/10.1039/C0DT00505C
Article type
Communication
Submitted
19 May 2010
Accepted
14 Jul 2010
First published
08 Sep 2010

Dalton Trans., 2010,39, 9484-9486

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Synthesis, structures and electrochemistry studies of 2Fe2S–Fe(II)(S–2N)2 models for H-cluster of [FeFe]-hydrogenase

M. Hu, H. Wen, C. Ma, N. Li, Q. Yan, H. Chen and C. Chen, Dalton Trans., 2010, 39, 9484 DOI: 10.1039/C0DT00505C

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