Initial employment of di-2-pyridyl ketone as a route to nickel(II)/lanthanide(III) clusters: triangular Ni2Ln complexes

Constantinos G. Efthymiou; Anastasia N. Georgopoulou; Constantina Papatriantafyllopoulou; Aris Terzis; Catherine P. Raptopoulou; Albert Escuer; Spyros P. Perlepes

doi:10.1039/C0DT00493F

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Initial employment of di-2-pyridyl ketone as a route to nickel(ii)/lanthanide(iii)clusters: triangular Ni₂Ln complexes†

Constantinos G. Efthymiou,^a Anastasia N. Georgopoulou,^b Constantina Papatriantafyllopoulou,^a Aris Terzis,^b Catherine P. Raptopoulou,^b Albert Escuer*^c and Spyros P. Perlepes*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Patras, Patras, Greece
E-mail: perlepes@patreas.upatras.gr
Tel: +30 2610 997146

^b Institute of Materials Science, NCSR “Demokritos”, Aghia Paraskevi Attikis, Greece

^c Departament de Quimica Inorganica, Universitat de Barcelona, Marti Franqués 1-11, Barcelona, Spain
E-mail: albert.escuer@qi.ub.es
Tel: +34 93 4039138

Abstract

Using monoanionic forms of di-2-pyridyl ketone as the only primary ligand, triangular Ni₂M (M = lanthanide, Y) complexes with interesting magnetic properties have been synthesized.

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Article information

DOI: https://doi.org/10.1039/C0DT00493F
Article type: Communication
Submitted: 18 May 2010
Accepted: 06 Jul 2010
First published: 03 Aug 2010

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Dalton Trans., 2010,39, 8603-8605

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Initial employment of di-2-pyridyl ketone as a route to nickel(II)/lanthanide(III) clusters: triangular Ni₂Ln complexes

C. G. Efthymiou, A. N. Georgopoulou, C. Papatriantafyllopoulou, A. Terzis, C. P. Raptopoulou, A. Escuer and S. P. Perlepes, Dalton Trans., 2010, 39, 8603 DOI: 10.1039/C0DT00493F

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Dalton Transactions