Issue 32, 2010
From the journal:

Dalton Transactions

Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation†

Laura J. Sewell,a   Adrian B. Chaplin,a   Joseph A. B. Abdallaa  and  Andrew S. Weller*a  

* Corresponding authors

a Department of Chemistry, Inorganic Chemistry Laboratories, University of Oxford, Oxford, UK
E-mail: andrew.weller@chem.ox.ac.uk

Abstract

[Rh(PtBuiBu2)2][BArF4], formed by removal of H2 from [RhH2(PtBuiBu2)2][BArF4], is in rapid equilibrium between C–H activated Rh(III) isomers, but reacts as a masked 12-electron [Rh(PtBuiBu2)2]+ Rh(I) cation.

Graphical abstract: Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation

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Article information

DOI
https://doi.org/10.1039/C0DT00449A
Article type
Communication
Submitted
10 May 2010
Accepted
18 Jun 2010
First published
12 Jul 2010

Dalton Trans., 2010,39, 7437-7439

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Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation

L. J. Sewell, A. B. Chaplin, J. A. B. Abdalla and A. S. Weller, Dalton Trans., 2010, 39, 7437 DOI: 10.1039/C0DT00449A

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