Issue 29, 2010
From the journal:

Dalton Transactions

Encapsulation of cyclooctatetraenyl dianion in an unusual organic/inorganic lanthanide triple-decker sandwich complex†

Volker Lorenz,a   Steffen Blaurock,a   Cristian G. Hriba  and  Frank T. Edelmann*a  

* Corresponding authors

a Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Universitätsplatz 2, Magdeburg, Germany
E-mail: frank.edelmann@ovgu.de
Fax: +49 391 6712933
Tel: +49 391 6718327

Abstract

Treatment of [(COT)Nd(THF)2(μ-Cl)]2 with dilithium tetraphenyldisiloxanediolate, (LiOSiPh2)2O, in a molar ratio of 1 : 4 afforded the novel organic/inorganic triple-decker complex (μ-η8:η8-COT)[Nd{(Ph2SiO)2O}2{Li(THF)2}{Li(THF)}]2 (1) which was structurally characterized by X-ray diffraction.

Graphical abstract: Encapsulation of cyclooctatetraenyl dianion in an unusual organic/inorganic lanthanide triple-decker sandwich complex

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Article information

DOI
https://doi.org/10.1039/C0DT00094A
Article type
Communication
Submitted
09 Mar 2010
Accepted
01 Jun 2010
First published
14 Jun 2010

Dalton Trans., 2010,39, 6629-6631

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Encapsulation of cyclooctatetraenyl dianion in an unusual organic/inorganic lanthanide triple-decker sandwich complex

V. Lorenz, S. Blaurock, C. G. Hrib and F. T. Edelmann, Dalton Trans., 2010, 39, 6629 DOI: 10.1039/C0DT00094A

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