Issue 37, 2010
From the journal:

Dalton Transactions

Correlating Pt–P bond lengths and Pt–P coupling constants†

Paul G. Waddell,a   Alexandra M. Z. Slawina  and  J. Derek Woollins*a  

* Corresponding authors

a School of Chemistry, University of St Andrews, St Andrews, Scotland
E-mail: jdw3@st-and.ac.uk

Abstract

The X-ray structures of (5) cis-PtBr2(P(OMe)3)2, (6) cis-PtBr2(P(OMe)2Ph)2, (7) cis-PtBr2(P(OMe)Ph2)2, (8) cis-PtBr2(PPh3)2, (9) cis-PtI2(P(OMe)3)2, (10) cis-PtI2(P(OMe)2Ph)2, (11) cis-PtI2(P(OMe)Ph2)2 and (12) cis-PtI2(PPh3)2 are reported and compared with the previously reported chloride analogues. The magnitude of the J{Pt–P} varies linearly with the Pt–P bond length (lPt–P = 2.421 −J/24255) for these 12 complexes.

Graphical abstract: Correlating Pt–P bond lengths and Pt–P coupling constants

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Article information

DOI
https://doi.org/10.1039/C003256E
Article type
Paper
Submitted
16 Feb 2010
Accepted
08 Jun 2010
First published
16 Aug 2010

Dalton Trans., 2010,39, 8620-8625

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Correlating Pt–P bond lengths and Pt–P coupling constants

P. G. Waddell, A. M. Z. Slawin and J. D. Woollins, Dalton Trans., 2010, 39, 8620 DOI: 10.1039/C003256E

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