Issue 14, 2010

First aryl-substituted acyclic imino-N-heterocyclic carbene ligand precursor: synthesis, characterisation and coordination with silver(i) and copper(i)

Abstract

The first aryl-substituted imino-N-heterocyclic ligand precursor was prepared and structurally characterised, along with the corresponding silver(I) and copper(I) chloride complexes. An unusual T-shape coordination mode for the copper centre was observed.

Graphical abstract: First aryl-substituted acyclic imino-N-heterocyclic carbene ligand precursor: synthesis, characterisation and coordination with silver(i) and copper(i)

Supplementary files

Article information

Article type
Communication
Submitted
18 Dec 2009
Accepted
18 Feb 2010
First published
02 Mar 2010

Dalton Trans., 2010,39, 3361-3365

First aryl-substituted acyclic imino-N-heterocyclic carbene ligand precursor: synthesis, characterisation and coordination with silver(I) and copper(I)

A. C. Badaj, S. Dastgir, A. J. Lough and G. G. Lavoie, Dalton Trans., 2010, 39, 3361 DOI: 10.1039/C002234A

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