Issue 36, 2010
From the journal:

Dalton Transactions

Compensation effect and volcano curve in toluene hydrogenation catalyzed by transition metal sulfides†

N. Guernalec,ab   C. Geantet,a   T. Cseri,b   M. Vrinat,a   H. Toulhoatb  and  P. Raybaud*b  

* Corresponding authors

a IRCELYON-CNRS, 2 avenue Albert Einstein, Villeurbanne, France
E-mail: christophe.geantet@ircelyon.univ-lyon1.fr
Fax: +33 472445399
Tel: + 33 4 72 44 53 36

b IFP, Direction Catalyse et Séparation, Rond-point de l’échangeur de Solaize, Solaize, France
E-mail: pascal.raybaud@ifp.fr
Fax: +33 4.78.02.20.66
Tel: +33.4.78.02.56.20

Abstract

Within the framework of volcano curves, a kinetic study of toluene hydrogenation catalyzed by transition metal sulfides highlights the variation of the apparent kinetic parameters as a function of the ab initio sulfur-metal bond energy descriptor and sulfo-reductive reaction conditions.

Graphical abstract: Compensation effect and volcano curve in toluene hydrogenation catalyzed by transition metal sulfides

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Article information

DOI
https://doi.org/10.1039/C001069C
Article type
Communication
Submitted
18 Jan 2010
Accepted
01 Apr 2010
First published
27 Apr 2010

Dalton Trans., 2010,39, 8420-8422

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Compensation effect and volcano curve in toluene hydrogenation catalyzed by transition metal sulfides

N. Guernalec, C. Geantet, T. Cseri, M. Vrinat, H. Toulhoat and P. Raybaud, Dalton Trans., 2010, 39, 8420 DOI: 10.1039/C001069C

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