Issue 34, 2010

Coordination between [H2P2W12O48]12− and antimony(iii): synthesis and characterization of sandwich complex derived from the new {P2W13O51} fragment

Abstract

A sandwich-type anionic cluster of a new lacunary building block [P2W13O51]14− has been prepared: [H6{P2W13O51}2Sb4]10− (1) was synthesized in a one-pot self-assembly reaction of [H2P2W12O48]12− with C4H4KO7Sb·0.5H2O and characterized by single-crystal X-ray analysis, IR, thermogravimetric analysis, elemental analysis, UV, NMR and electrochemistry. 1 represents the first dimetric, antimony-containing polyoxoanion derived from a vacant Dawson-type tungstophosphate.

Graphical abstract: Coordination between [H2P2W12O48]12− and antimony(iii): synthesis and characterization of sandwich complex derived from the new {P2W13O51} fragment

Supplementary files

Article information

Article type
Paper
Submitted
07 Dec 2009
Accepted
10 Jun 2010
First published
29 Jul 2010

Dalton Trans., 2010,39, 8033-8037

Coordination between [H2P2W12O48]12− and antimony(III): synthesis and characterization of sandwich complex derived from the new {P2W13O51} fragment

C. Zhang, S. Liu, F. Ma, R. Tan, W. Zhang and Z. Su, Dalton Trans., 2010, 39, 8033 DOI: 10.1039/B925682B

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