3D MnII coordination polymer with alternating azide/azide/formate/formate bridged chains: synthesis, structure and magnetic properties

Jiong-Peng Zhao; Bo-Wen Hu; Qian Yang; Xiao-Feng Zhang; Tong-Liang Hu; Xian-He Bu

doi:10.1039/B919048A

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3D Mn^II coordination polymer with alternating azide/azide/formate/formate bridged chains: synthesis, structure and magnetic properties†

Jiong-Peng Zhao,^a Bo-Wen Hu,^a Qian Yang,^a Xiao-Feng Zhang,^a Tong-Liang Hu^a and Xian-He Bu*^a

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* Corresponding authors

^a Department of Chemistry, Nankai University, Tianjin 300071, China
E-mail: buxh@nankai.edu.cn
Fax: +86-22-23502458

Abstract

A new 3D Mn^II coordination polymer, [Mn₂(HCO₂)(L)₂(N₃)·MeOH]_∞ (1) (L = nicotinate N-oxide), was synthesized by a solvothermal reaction and characterized magnetically. Complex 1 is a typical antiferromagnet with alternating azide/azide/formate/formate bridges, exhibiting a new –J₁J₁J₂J₂– coupling sequence. This is the first complex to contain an azide, formate and another type of carboxylate ligand.

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Article information

DOI: https://doi.org/10.1039/B919048A
Article type: Communication
Submitted: 14 Sep 2009
Accepted: 12 Oct 2009
First published: 28 Oct 2009

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Dalton Trans., 2010,39, 56-58

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3D Mn^II coordination polymer with alternating azide/azide/formate/formate bridged chains: synthesis, structure and magnetic properties

J. Zhao, B. Hu, Q. Yang, X. Zhang, T. Hu and X. Bu, Dalton Trans., 2010, 39, 56 DOI: 10.1039/B919048A

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