Issue 3, 2010
From the journal:

Dalton Transactions

A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope†‡

Richmond Lee,§‡a   Yuanyong Yang,‡a   Geok Kheng Tan,a   Choon-Hong Tan*a  and  Kuo-Wei Huang§*a  

* Corresponding authors

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore
E-mail: chmtanch@nus.edu.sg, kuowei.huang@kaust.edu.sa
Tel: +65-6516 2845

Abstract

A novel paddlewheel or ‘lantern’ heteroleptic diruthenium guanidinate complex Ru2(TBO)2(OAc)2Cl·3MeCN (1·3MeCN) was synthesized and structurally characterized. Compared with a known tetra-substituted di-ruthenium guanidinate complex Ru2(TBD)4Cl, 1 revealed structural dissimilarities with internal twisting.

Graphical abstract: A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope

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Article information

DOI
https://doi.org/10.1039/B915881B
Article type
Communication
Submitted
03 Aug 2009
Accepted
30 Sep 2009
First published
19 Oct 2009

Dalton Trans., 2010,39, 723-725

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A Novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: Synthesis, structure, and scope

R. Lee, Y. Yang, G. K. Tan, C. Tan and K. Huang, Dalton Trans., 2010, 39, 723 DOI: 10.1039/B915881B

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