Ligand substitution behavior of Ru6(μ6-C)(CO)17 with unsaturated diphosphines: facile capping of a polyhedral face and photochemically promoted P–C bond cleavage in the clusterRu6(μ6-C)(CO)14(μ3-bpcd)†
Abstract
The ligand substitution chemistry of the CHPPh2 (
C(PPh2)C(O)CH2C(O)](μ-PPh2) (6) in essentially quantitative yield. The reaction between 1 and the ligand