Issue 6, 2010
From the journal:

Dalton Transactions

Palladium complexes of 6-aminofulvene-2-aldiminate (AFA) ligands†

Philip J. Bailey,*a   Anna Collins,a   Peter Haack,a   Simon Parsons,a   Mahmudur Rahman,a   Damian Smitha  and  Fraser J. Whitea  

* Corresponding authors

a School of Chemistry, University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh, U.K.
E-mail: Philip.Bailey@ed.ac.uk
Tel: +44(0)131 650 6448

Abstract

Bis(N,N′-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine (4) has been synthesised and characterised. The synthesis and characterisation of two zwitterionic Pd(II) complexes [(Ph2AFA)Pd(Me)DMAP] (1) and [(Ph2AFA)Pd(N,N-dimethylbenzylamine-2-C,N)] (2) are reported. Activation of 1 and 2 for ethene polymerisation with Lewis acids such as BF3 and B(C6F5)3 were not successful. Attempted synthesis of halide-bridged dimers of the form [(Ph2AFA)Pd(μ-X)]2 resulted in formation of bis-chelated complexes [(Cy2AFA)2Pd] (3) and [(tBu2AFA)2Pd] (5).

Graphical abstract: Palladium complexes of 6-aminofulvene-2-aldiminate (AFA) ligands

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Article information

DOI
https://doi.org/10.1039/B914707A
Article type
Paper
Submitted
21 Jul 2009
Accepted
18 Nov 2009
First published
04 Dec 2009

Dalton Trans., 2010,39, 1591-1597

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Palladium complexes of 6-aminofulvene-2-aldiminate (AFA) ligands

P. J. Bailey, A. Collins, P. Haack, S. Parsons, M. Rahman, D. Smith and F. J. White, Dalton Trans., 2010, 39, 1591 DOI: 10.1039/B914707A

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