Issue 7, 2010
From the journal:

Dalton Transactions

A chiral screw propeller-like scalene triangle manganese(iii)cluster†

Cai-Ming Liu,*a   De-Qing Zhanga  and  Dao-Ben Zhua  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China
E-mail: cmliu@iccas.ac.cn

Abstract

The screw propeller-like cluster complex [Mn3(OMe)(LSchiff)3(H2O)Cl2]·2H2O {H2LSchiff = 2-[(E)-(R)-1-hydroxypropan-2-ylimino]methyl-6-methoxyphenol} is the first chiral triangle manganese cluster compound. It is also a rare nonsymmetrical triangle compound with an unequilateral arrangement of three manganese(III) atoms. Both ferromagnetic and antiferromagnetic interactions exist between the Mn3+ ions, exhibiting a magnetic anisotropy.

Graphical abstract: A chiral screw propeller-like scalene triangle manganese(iii) cluster

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Article information

DOI
https://doi.org/10.1039/B913062D
Article type
Paper
Submitted
01 Jul 2009
Accepted
20 Nov 2009
First published
04 Jan 2010

Dalton Trans., 2010,39, 1781-1785

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A chiral screw propeller-like scalene triangle manganese(III) cluster

C. Liu, D. Zhang and D. Zhu, Dalton Trans., 2010, 39, 1781 DOI: 10.1039/B913062D

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