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Issue 2, 2010
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U(iv) and U(v) azide complexes supported by amide or aryloxide ligands

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Abstract

The uranium(IV) azides [Li(THF)3]2[U(OAr)4(N3)2], Ar = 2,6-Me2C6H3, and {[Na(THF)4][U[N(SiMe3)2]3(N3)2]}x have been synthesised and structurally characterised. Oxidation of these complexes affords [Li(THF)3][U(OAr)5(N3)] and U[N(SiMe3)2]3(N3)2, which are the first azides of U(V).

Graphical abstract: U(iv) and U(v) azide complexes supported by amide or aryloxide ligands

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Supplementary files

Article information


Submitted
19 May 2009
Accepted
13 Jul 2009
First published
24 Jul 2009

Dalton Trans., 2010,39, 352-354
Article type
Communication

U(IV) and U(V) azide complexes supported by amide or aryloxide ligands

S. Fortier, G. Wu and T. W. Hayton, Dalton Trans., 2010, 39, 352
DOI: 10.1039/B909879H

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