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Issue 31, 2010
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Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

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Abstract

The study of solubility of 4-nitroaniline and its N,N-diethyl derivative in ionic liquids (ILs) of varying water content has shown that it is the interaction between water and the ILs’ ions, and not with the solute, that is the most important factor determining the solute's preferential hydration parameter and thus the solvation shell structure.

Graphical abstract: Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

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Article information


Submitted
16 Sep 2009
Accepted
29 Apr 2010
First published
18 Jun 2010

Phys. Chem. Chem. Phys., 2010,12, 9063-9066
Article type
Paper

Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

L. Wright, M. W. Sanders, L. Tate, G. Fairless, L. Crowhurst, N. C. Bruce, A. J. Walker, G. A. Hembury and S. Shimizu, Phys. Chem. Chem. Phys., 2010, 12, 9063
DOI: 10.1039/B919348K

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