Investigating the electronic structure and bonding in uranyl compounds by combining NEXAFSspectroscopy and quantum chemistry
Abstract
The nature of the reactivity of the “O bond. In this paper, a combination of near-edge X-ray absorption fine structure (
O bonding in two
O bond, we observe that the electron-donating or withdrawing character of the equatorial ligands has a measurable effect on features in the NEXAFS