Issue 31, 2010

pH-Controlled twisted intramolecular charge transfer (TICT) excited state via changing the charge transfer direction

Abstract

In this work, a new model compound, the twisted intramolecular charge transfer (TICT) excited state of Milrinone (MIR), has been theoretically presented. MIR exists in different tautomeric and ionic forms in aqueous solution with different pH values. The TICT excited state properties for various forms of MIR are demonstrated to be significantly different and controlled by the pH values of MIR in aqueous solution.

Graphical abstract: pH-Controlled twisted intramolecular charge transfer (TICT) excited state via changing the charge transfer direction

Supplementary files

Article information

Article type
Paper
Submitted
23 Nov 2009
Accepted
15 Apr 2010
First published
16 Jun 2010

Phys. Chem. Chem. Phys., 2010,12, 8914-8918

pH-Controlled twisted intramolecular charge transfer (TICT) excited state via changing the charge transfer direction

G. Zhao and K. Han, Phys. Chem. Chem. Phys., 2010, 12, 8914 DOI: 10.1039/B924549A

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