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Issue 1, 2010
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Hybrid polyoxometalate clusters with appended aromatic platforms

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Abstract

The assembly of polyoxometalate architectures based on Mn-Anderson clusters capped with different aromatic platforms via the ‘Tris’ linker (Tris = tris(hydroxymethyl)aminomethane), allows the formation and isolation of four new hybrid polyoxometalate clusters of 2–5 with the general composition of [n-N(C4H9)4]3[MnMo6O18{(OCH2)3CN = CH-R}2]·solv., (R = –(C6H5) 2, –(C6H5O) 3, –(C11H8N) 4 and –(C13H9) 5; solv. = MeOH or H2O). These compounds were obtained simply by the reaction of compound 1, ([n–N(C4H9)4]3[MnMo6O18{(OCH2)3CNH2}2]), with the corresponding aldehyde and the aromatic platforms were chosen to explore the design principles for covalently constructed POM aromatic–organic–inorganic hybrids.

Graphical abstract: Hybrid polyoxometalate clusters with appended aromatic platforms

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Supplementary files

Article information


Submitted
27 May 2009
Accepted
04 Aug 2009
First published
27 Aug 2009

CrystEngComm, 2010,12, 109-115
Article type
Paper

Hybrid polyoxometalate clusters with appended aromatic platforms

Y. Song, D. Long and L. Cronin, CrystEngComm, 2010, 12, 109
DOI: 10.1039/B910434H

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