Issue 11, 2010
From the journal:

CrystEngComm

Tubular crystals growth for a nanoporous hydrogen-bonded metal–organic framework†

Georges Mouchaham,ab   Nans Roques,ab   Abdellah Kaiba,c   Philippe Guionneauc  and  Jean-Pascal Sutter*ab  

* Corresponding authors

a CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, Toulouse, France
E-mail: sutter@lcc-toulouse.fr
Fax: (+33) 561-333-003
Tel: (+33) 561-333-157

b Université de Toulouse, UPS, INPT, LCC, Toulouse, France

c CNRS, Université de Bordeaux, ICMCB, 87 Av. Doc. A. Schweitzer, Pessac, France
Fax: (+33) 540-002-678

Abstract

A supramolecular architecture formed by H-bonded assemblage of ditopic bisimidazoliumbenzene cations with anionic metal-oxalate modules shows permanent porosity upon guests release; the reversible sorption process being accompanied by crystal-to-crystal transformations. Additional macroporosity for the material was achieved by controlled growth of crystals with tubular morphology.

Graphical abstract: Tubular crystals growth for a nanoporous hydrogen-bonded metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C0CE00256A
Article type
Communication
Submitted
12 Mar 2010
Accepted
24 Jun 2010
First published
30 Jul 2010

CrystEngComm, 2010,12, 3496-3498

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Tubular crystals growth for a nanoporous hydrogen-bonded metal–organic framework

G. Mouchaham, N. Roques, A. Kaiba, P. Guionneau and J. Sutter, CrystEngComm, 2010, 12, 3496 DOI: 10.1039/C0CE00256A

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