Issue 11, 2010

Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

Abstract

CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl2], the disubstituted [Co(H2L)2][PF6]2, and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [{Co(H2L)2}(H2L)4][PF6]2, as illustrated by X-ray crystal structure analysis.

Graphical abstract: Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

Supplementary files

Article information

Article type
Communication
Submitted
25 Mar 2010
Accepted
04 Jun 2010
First published
06 Jul 2010

CrystEngComm, 2010,12, 3422-3424

Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

T. R. Scicluna, B. H. Fraser, N. T. Gorham, J. G. MacLellan, M. Massi, B. W. Skelton, T. G. St Pierre and R. C. Woodward, CrystEngComm, 2010, 12, 3422 DOI: 10.1039/C0CE00036A

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